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"Adiós" was released as the lead single from A Quien Quiera Escuchar; it premiered on September 22, 2014 on Uforia´s radio stations in the United States and Puerto Rico and was released to digital retailers on September 23 in three versions, Spanish, English and English-French. "Adiós" is a world music-flavored song with a length of three minutes and fifty-eight seconds. The single features "original sound" and influences from throughout different parts of the world in which Martin traveled in 2014. Reviewer Haley Longman of OK! praised Martin´s multilingualism and wrote that with "Adiós" he transformed it in a song form. The single debuted at number 22 on the US Billboard Hot Latin Songs chart becoming his 41st entry on the chart. Following Martin´s performance at the 15th Annual Latin Grammy Awards, "Adiós" jumped from number 16 to number nine on the Hot Latin Songs chart and became the singer´s 24th top-ten single on the chart. With that feat, it pushed Martin ahead of singer Gloria Estefan on the list of acts with the most top-ten hits on the chart.